Be very careful with Rome2Rio. I would only use it as a first brush at determining transportation. It has been known for erroneous information or not including all options. I prefer Google Maps.
There is so much to do In Padua and Venice. I don't consider either to be a day trip. They are about an hour and a half each direction on public transportation. I don't really consider it difficult to get into or out of Venice, but it can take multiple forms of transportation.
I have not yet been to Ravenna, but I sure would like to get there. It could make sense to fly into Venice stay a few nights, then head to Padua for a few nights, then Ravenna, and end in Bologna to fly home. But, you really need to play with flights to see what flight times you'd have available. For example, I once planned a trip to start in Rome and end in Naples. When I found out I could only fly home at 6am from Naples, I switched my itinerary to fly into Naples and out of Rome.
You will find that there are many styles of travel. Some pack larger bags and check them, while others only bring carry on luggage. Some like to have limited "base cities" and do many day trips. For myself, I pack in a carry on bag with packing cubes and can pack up in just a little more time than it takes me to get ready in the morning. The logistics have to be really bad or a place would have to be very special for me to travel more than 2.5 hours on "day trips". I find long hours on a train exhausting and I don't like the "backtracking" and much prefer staying at a place for a few nights and then move on to another town.
When we were in Venice in 2025, it was very crowded, as it always is. One way to deal with the crowds and see what we want to see was to be out at 7:30am. The city was so pleasant until about 9:30am. Likewise, it calmed down around 5/6pm. When you overnight in a city, you can see the city without a bunch of day trippers.
When we stayed in Padua we did day trips to Vicenza and Verona. Venice is a more expensive place to stay so my inclination would always be to stay in Venice to see Venice and stay elsewhere to see places beyond Venice.