You didn’t say when? That does change things. So I will assume March thru October.
Lots of choices as the list above illustrates. All are good. But I only talk about what I know and that’s obviously not for everyone.
Sounds as though you like city destinations. If at least half the trip could be more rural I would suggest Montenegro (list of video links here: https://community.ricksteves.com/travel-forum/montenegro/podgorica-to-dubrovnik-by-car). But if the majority is city, then, among the others listed above, Budapest
Walkability: Walking alone, maybe an 8. But the surface trams are great tour busses and they open a way to reach other locations within the city to explore on foot. So if you throw that in I give it a 10.
https://youtu.be/14e80xGLxSI?si=8Ebu_PCWqZPG4fgz
https://youtu.be/nOAlQxuQZWE?si=HkVbFwYPvQntijId
https://youtu.be/SLQffU693a8?si=EqP-AGDH_f_G5YDs
Great food: Lots of places can boast good food and wine, Budapest has a remarkable food scene as well. From Michelin star to purely home cooking in a local setting. And as you would expect from a large city there are restaurants representing every corner of the world. Hey, you don’t go to Chicago and only eat pizza. You go for the world and world class dining.
https://youtu.be/QborfsYrmMA?si=AKTccJQgYXaokxr8
And wine: Some of Europe’s best wine. But produced in mom and pop wineries so not much exported. Wine is a way of life here. A place where you can take a short trip out to a winery and meet the man and family that makes the wine. Wander the cellars and sample the product … in a beautiful very local and low key setting. Not a wine chateau tour.
https://youtu.be/1AJtDHOJMvk?si=-A05PvtCNYDqpzjS
https://youtu.be/TrfTpCgpUls?si=CjRCDQ-WYeNRSsmz
Beautiful art/interesting historical sites: You will not find a more beautiful city in Europe. That’s subjective so you may find one you think “AS” beautiful. The history here is more recent than many and that makes it more accessible and more relevant in a lot of ways. Communism, russian occupation, holocaust, Austro-Hungarian Imperialism of the 18th and 19th centuries. Easy to understand in today’s terms and fascinating in that some of it is relevant today.
https://youtu.be/QndU3I1mfqo?si=TaIEnhJCxJwbl_lp
https://youtu.be/lZUR-GJLAgY?si=gsYtz3unnfPHPtQ8
https://youtu.be/LEQJpzKqd9I?si=pYrp0bfNwo14xZy1
https://youtu.be/sXBr7lxSVp4?si=ZuJVyG2SG7_mg2IS
Possibility a second destination within reasonable travel distance: 2.5 hours to Vienna for a very different experience or any number of Hungarian short trips.
https://youtu.be/OUuA501Wpts?si=PH-Xk5EHoiBPnBYe
https://youtu.be/pj4EyxKu6vc?si=Hcd9sUpEXVtbMi1z