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Train from Venice to Florence and Florence to Rome

I will be travelling from Venice - Florence and Florence - Rome by train...is best to get with point-to-point ticket right ?

I heard that we can only purchase rail ticket / pass online if we have Europe credit card ..I'm Canadian I have to get it in person when I get to Italy right ?

If so...do Venice Airport sells train I need and I'm able to get reservation in such short notice (I'm only staying in Venice for 1 night and will head to Florence)

Any advise is good.