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Taxi availability and price in Siena and Chiusi

I have planned our honeymoon in Italy in June. I was just looking at Rick's book on Italy and noticed that there are no buses on Sunday from Siena to Montepulciano or Chiusi to Montepulciano and Sunday is the day we will check in to our hotel in Montepulciano. I have a few questions. Are there taxis available to go to Montepulciano from Siena and/or from Chiusi? What would be a cheaper option? Just to take a taxi from Siena to Montepulciano or ride the train from Siena to Chiusi and take a taxi from Chiusi to Montepulciano? Thank you!