FLIGHT Paris train station to Munich Train Station 
To Airport from Paris Est 0:45, Early Arrival 2:00, CDG to MUC  01:30 minutes, Delays 0:30, Deplaning 0:30, MUC to Munich Train Station 0:45:  Total time:  6:00
TRAIN Paris to Munich
Early arrival 0:30 (15 minutes if you are the sort of person that does not need to ask the sorts of questions that the OP is asking), Train 6:00:  Total time:  6:30
Theoretically the flight is an hour faster, but let’s say it’s a wash, and it’s about what you think will be a easier journey.  I would fly.  I hate being stuck is a seat for 6 hours.  
FLIGHT Frankfurt to Paris
To FRA from Frankfurt Central:  0:15,  Early Arrival:  2:00, Flight:  1:30, Delays: 0:30, Deplaning:  0:30, GDG to Paris Est 0:45, Total time  5:30   
TRAIN Frankfurt to Paris
Early arrival 0:30 (15 minutes if you are the sort of person that does not need to ask the sorts of questions that the OP is asking), Train 4:00, Total time:  4:30    
Theoretically the train is an hour faster, but I still think it’s about what you think will be an easier journey.  This one I would consider the train because my tolerance for a train ends at about 4 hours.  Might come down to where my accommodations are located.  Closer to the airport or the train station.  Or flip a coin.   
But neither is "better" for everyone.