FLIGHT Paris train station to Munich Train Station
To Airport from Paris Est 0:45, Early Arrival 2:00, CDG to MUC 01:30 minutes, Delays 0:30, Deplaning 0:30, MUC to Munich Train Station 0:45: Total time: 6:00
TRAIN Paris to Munich
Early arrival 0:30 (15 minutes if you are the sort of person that does not need to ask the sorts of questions that the OP is asking), Train 6:00: Total time: 6:30
Theoretically the flight is an hour faster, but let’s say it’s a wash, and it’s about what you think will be a easier journey. I would fly. I hate being stuck is a seat for 6 hours.
FLIGHT Frankfurt to Paris
To FRA from Frankfurt Central: 0:15, Early Arrival: 2:00, Flight: 1:30, Delays: 0:30, Deplaning: 0:30, GDG to Paris Est 0:45, Total time 5:30
TRAIN Frankfurt to Paris
Early arrival 0:30 (15 minutes if you are the sort of person that does not need to ask the sorts of questions that the OP is asking), Train 4:00, Total time: 4:30
Theoretically the train is an hour faster, but I still think it’s about what you think will be an easier journey. This one I would consider the train because my tolerance for a train ends at about 4 hours. Might come down to where my accommodations are located. Closer to the airport or the train station. Or flip a coin.
But neither is "better" for everyone.