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Bus from montepulciano to siena

I am going to pick up a friend that will be traveling to Siena on a bus from montepulciano. Does anyone know where that bus stops in Siena? Do you know if the bus runs often?

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I've done the same bus journey some years ago.
This is a link to the timetables of the company: http://www.tiemmespa.it/index.php/Viaggia-con-noi/Orari-e-linee/Siena/Extraurbano You are looking for bus number 112.
One of the bus stops is at the railway station in Siena. I remember it being somewhat confusing because of the series of escalators going up from the station to the city, and the exit sign for the bus stop somewhat awkwardly in a corner. You need to get out at a place with a supermarket in front of you. (I bought some oranges there.)

Another bus stop is near one of the city gates: Porta Ovile. It is not so confusing, but let your friend check the bus actually will stop there!