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Booking the night train from Barcelona to Madrid

I'll be in Spain the first couple weeks of September and traveling on the night from Barcelona from Madrid the first week. Is it necessary to book it before I leave? I've attempted to do so via Tik Net on the Renfe site but am having trouble setting up a New User Account. Any suggestions?

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We are going from Barcelona to Madrid and I just booked an incredibly cheap ticket on the Vuerling airlines. The trip takes an hour and fifteen minutes and cost about 40 euro each--round trip. Check them out unless you just want to go by train. It would save some time and I think the train is much more expensive.
Donna