train from Ljubljana to rental car in rijeka

We are taking the train from Ljubljana to Rijeka to pick up our Croatian rental car. Are there car rental offices in downtown Rijeka or must we get to the Rijeka airport to get a car? Are the rental offices easy to find from the train station? Since we are doing this on a Saturday are the offices closed at 12:00 for the rest of the day? How long is the train ride from Ljubljana to Rijeka?

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