What is the best way to get to Toledo on Oct. 24th, going out in the morning and back that night?
The Renfe train line is the best way to go. The first link has the October 24th train schedule.
https://madridfoodtour.com/a-culture-packed-day-trip-to-toledo-from-madrid/
You may want to prebook as sometimes the trips of choice are booked up - particularly the return trips.
Thank you. Just booked my ticket per the link successfully!
You can also go by public bus or Blablacar