We are planning part of our honeymoon in Barcelona in early May. Looking for hotel suggestions in the luxury romantic category but that would be not the big scale generic brand of hotel.
Thanks
The Neri in the older section of Barcelona is absolutely lovely and charming. It would be a very special and memorable place for a honeymoon.
The Alma Barcelona is also very special. It has a very modern decor.
Both are special in different ways. If you will be in Barcelona for several days, maybe split your time between the two, which is what we did in March last year. Each of the two locations provides a feel for two different (but both very nice) neighborhoods and the resulting convenience for sights in the two different areas of Barcelona.
Happy travels.
Totally agreeing with @Wonderful, luxury can be very expensive in Barcelona and same as romantic, these concepts differ from person to person. As does the style and preferences.... and budget.
Yet, here you have a short list of some mixed options for nice "non-big scale generic brand" hotels that might or might not suit you, note Barcelona has dozens of hotels like these:
Hotel Neri and Hotel Alma (thnks Margaret), Hotel 1898, Hotel DO Plaça Reial, Hotel Duquesa de Cardona, Casa Fuster, Hotel Mercer, Hotel Villa Emilia, Hotel El Palauet, Hotel Ohla Barcelona, Hotel Pulitzer, Hotel Espanya, Hotel Abac, Circa 1905 B&B, Hotel Bagués, Hotel Murmuri, Hotel H10 Montcada, Hotel Gran Derby Suite, Claris Hotel, The 5 Rooms Apartments, Milton House Apartments, Sixty-Four Apartments, Hotel Primero Primera, Hotel Mandarin Oriental...
Unfortunately I cannot recommend you one or another: I do live here, have little use for these and don't work in tourism.
As well as the Alma and the Neri as mentioned...
http://www.almabarcelona.com/
http://www.hotelneri.com/en/
...here are 6 more to check out.
http://www.ohlahotel.com/
http://www.casacamper.com/
http://www.hotelcasafuster.com/en/
http://www.mercerbarcelona.com/en
http://www.grandhotelcentral.com/
http://www.hoteldoreial.com/en/