From Puerta del Sol you are close to the Plaza Mayor and the San Miguel market. Are you going to the Royal Palace and the Almudena cathedral across the plaza from the palace? That is also not too very far from your area. How about El Retiro Park? Lots to see there. If you are flea market fans, try El Rastro, held on Sundays, but expect crowds.
Will you be on a tour to actually visit sites or is it a bus tour? With the list of streets you give it makes me wonder if it is just a driving tour around the city. Do you like art? I see you plan to visit El Prado but the Reina Sofia museum is also nearby. If you are big soccer fans, try a visit to Santiago Bernebeu stadium, home of Real Madrid football club.
I see your itinerary includes Segovia (which you will enjoy very much) but are you going to any other destinations in Spain after Madrid? If so, save the flamenco show for Andalucía.
I like to recommend nearby Toledo but I don't think you have enough time. Same for El Escorial. With so little free time i would stay in the city.