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What to do between Montepulciano and Rome

We will be leaving Montepulciano around 9 am returning to Rome. The car will be returned to the Hertz rental place near the Vatican, we have done this before. I was wanting some suggestions of places to stop before we return to Rome. We have been to Civita and Orvieto. Any other towns worth a visit?
Dana

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715 posts

Castiglione del lago which is a bit east of Montepulciano. Pitigiliano and Sorano to the south west. Get lost on some white roads.