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What's your favorite hill towns in Tuscany

I will be doing a road trip in Tuscany for 6 days in second of week of September. I have already an itinerary. I just want to know what's your favorite hill towns. My home base is in Pienza and I will visit the towns of Cortona, Montepulciano, San Quirico d'Orcia, Montalcino, and Volterra.