Don't worry about this transfer - for several specific reasons.
1) You won't be allowed to miss any necessary steps. It's not like you can bypass immigration or customs or security, then get in trouble. These things aren't optional; if they're required, you won't be able to proceed without going through them.
2) Just follow the crowds. Many of the people getting off your plane will be going to the same places you are. Some, of course, will be going to other places, but it's not like you have to figure this out all by yourself. However, do make sure you don't follow someone who's going to another destination. For instance, someone connecting in Amsterdam to Morocco will not be going through passport control, whereas you need to.
3) Amsterdam is a well labeled airport. Remember that no one in the airport (airlines, security, etc) wants you getting lost or missing planes; it just makes more work for them! So, they really do try to make it straightforward.
If at any point you are lost or unsure, be sure to ask someone for help right away.
Have the flight number of your AMS to VCE flight handy. I find that, tired and jet lagged, I keep forgetting it, and since there can be multiple flights on multiple airlines, all going to the same place, you do need to make sure you go to the right gate for YOUR flight!