If I recall, from T3, once you get into the arrivals hall, look for signs for the trains. When we were there in September, it was slightly confusing, since they had some places cordoned off for the purposes of routing incoming people through checks (temperature, covid card, etc.) so outgoing people were routed slightly out of the way. But you will go down an elevated walkway towards the parking garages, I believe you wind up taking a right turn, and then up ahead a left turn which will lead you onto the platform area, with something like 4 tracks straight ahead.
If you did not get a ticket in T#, there are more ticket machines, very easy to use, take cash or card (some maybe card only), or there is a ticket counter.
Get your ticket, look at the schedule board, that will tell you what track the train is on, but the Leonardo Express is pretty obvious, and there are only two different trains (sometimes a third) that leave from there.
Relatively new is a Metro/subway type turnstyle that you put your ticket into to get to the train, I believe this negates the need to validate your ticket separately (an old problem and source of stories of 50 euro fines for many travelers).
From there, sit back, enjoy the not very spectacular scenery (but it is Italy!), the next stop is Termini.
The arrival track for the express used to be, and I believe still, is way on the side of the tracks, and down a ways, meaning a bit of a hike to get to the main platform area in Termini. From there, use the schedule board to find your track. If your train is an hour or more from leaving, it may not yet be listed, or have a track. The fast trains tend to leave from a common set of track, so if you see other fast trains, it will likely be in that area, if you are taking a regional train, probably on one of the other tracks. Use your departure time and train number as a clue as to where to look on the board/monitor, keep in mind that your train to S M Novella, might show as Venice (Venezia St. Lucia or Mestre for example) as that might be the last stop, with SMN being an intermediate stop. During covid, they also set up a security/document check going onto the actual platforms, and preferred you to wait until near your departure time to head to the platform. That may have all changed by the time you are there.