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Siena to Volterra by bus?

Hello --- Has anyone taken a bus from Siena to Volterra? If so how long did it take. We've heard you can take the Bus/Train from Pisa to Volterra but Siena looks far closer.

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It's only about 33 miles from Siena to Volterra, however the buses go around the world to get there. There are no trains going in that direction. You might check if a guided tour if available.
We rented a car to see the region, and visited San Gimignano and Volterra in about a half day when staying at an agriturismo.