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Rome to Volterra roundtrip

Hi!

I am travelling to Rome and Volterra the first week of May. I will be heading to Volterra from Rome on Wednesday the 5th and heading back to FCO airport on Saturday. Time doesn't matter on Saturday - the later the better, since my flight home isn't until early Sunday morning and I will be crashing at the airport Sat. night.
What's the best way to get to Volterra without driving? Train to Cecina, then a bus? Siena? Florence? What time should I leave Rome Termini? I'm having problems 1.) trying to find bus schedules that aren't confusing and 2.) coordinating the arrival/departure times with the train schedules. Any advice? Thanks so much!
~C