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Rental Car D'Orcia to Florence

We currently have a car we will pick up in Orvieto and return in Florence. Then we plan to spend a night or two in Florence. We are currently dropping it off at the train station, but we are a bit nervous about that. We have a b&b at the train station and plan to walk to the sights we want to see in Florence. Any suggestions or help as far as dropping the car off at the strain station in Florence? Thanks so much!