We will be arriving on Monday, Nov. 7,2022 by cruise ship. We r scheduled in port from 6am till 6pm. We r interested in hiring a driver/tour guide from the port to Volterra and also San Gimignano. We r open to other suggestions but have already visited Florence and Lucca.
Also, is it worth visiting Ischia from cruise terminal in Naples at the beginning of November
No personal experience, but you can try a google search using the following key words:
NOLEGGIO CON CONDUCENTE LIVORNO
This may be a stretch but the RS recommended Turislucca runs a number of Livorno cruise based excursions:
https://en.turislucca.com/
They don't offer one for Volterra but they offer several others - Lucca, Pisa, Florence, wine country etc - and they might willing to modify a tour to your requests.
And if not maybe they can recommend someone who can?
FWIW I took one of their Lucca walking tours and really enjoyed it.
Good luck,
=Tod
This may give you a place to start for Livorno.
https://www.livorno-shore-excursions.com/livorno-to-volterra-san-gimignano/
Ischia would be a nice day trip from Naples.