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Day trips from Florence...

Hello,
My mom (67 years old) and I will be in Florence for 5 days at the beginning of September (followed by 5 days in Barcelona). We have a couple of days set aside for museums and walking around to enjoy Florence, but will also be doing this full day trip to Cinque Terre.
http://www.grayline.com/tours/florence/best-of-cinque-terre-low-cost-5856_162/

We would also like to experience the Tuscan countryside and visit a vineyard/winery, but don't want that to be a full day. Would something like this be a good option? http://www.grayline.com/tours/florence/chianti-authentic-experience-with-delicious-wine-tasting-in-a-castle-5856_34/
Are there other suggestions for a vineyard/winery experience in the countryside? We'd prefer to do this in the evening.

Thank you!