CDG has a lot of separate terminals, it could help you to know which terminal are you landing into and where are you departing from. Probably, but absolutely not sure and I can't take responsability, you will be arriving at 2E and departing from 2F: in this case just the bare transfer would need 30 minutes, then add on top the time for immigration and security checks. (You have to do immigration, that is passport control in Paris, as Paris to Florence flight is internal to Schengen zone, so no immigration controls in Florence).
In my experience with a couple of similar cases, it can be done in one hour but it is a frantic thing and you really have to hope there is no delay in the incoming flight; in a case I have made it only for a delay in the outgoing flight.
The CDG structure with separate terminals may get really difficult to navigate - help yourself by studying a map in advance and there is also a website showing you, with appropriate photos, the itinerary to do. But if terminals are completely separate - for example you need to switch to terminal 2G, that involves waiting and then a 10 minutes shuttle bus run, a single hour is too short.