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Chianciano Terme

We will be picking up our car in Chiusi at 11:00. Our check in at our Agriturismo near Montepulciano isn't until 3 or 4. We will be driving through Chianciano Terme. Does anyone have information on visiting the thermal spas on a day visit? I couldn't find anything specific on the website. I thought this might be a relaxing way to spend a few hours after an early morning and long train ride!