We are staying at a hotel right in Syntagma square. We have arranged for a car rental with Athen Car Rental company. We are taking the car from Athens to Pelopennese. ACR can either drop off the car at our hotel or we can do the pickup from the airport. But, it is a trek - will need to take a taxi with bags, etc. down to the airport only to come right back up. Cost is not a concern as ACR charges for Athens city drop off but it's more about the convenience/hassle. ACR folks have told us that taking the A8 from Syntagma Square is straightforward but I wanted to get your thoughts. We will be driving out of Athens at around 9am.
We do tend to be super cautious and conservative.