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Athens to Astakos

Hi! I am planning a trip to Greece in September.
After landing in Athens and spending a couple of days there, I want to take a bus to Astakos and from there a ferry to Ithaka.
I have all the information about the ferry but almost none about the bus.
I know that it workes once a day every day and that the ride takes 3:40 hours.
But : Where to take it? AT WHAT TIME? Does the bus have a toilette? Is there a stop on the way? How much does the ticket cost? And where do I buy it?
Thanks in advance for any helpfull direction. Gabriela