1.) No.
The German Rail Pass covers trains only - all trains.
The Deutschland-Ticket covers regional trains and all buses, trams, subways. Not ICE or other long-distance trains. Please read about it carefully. It is available by subscription only andcovers an entire calendar month.
2.) There's a Freiberg near Dresden. ICE is not needed. There are other Freibergs too. Freiburg might be in extreme southwest Germany (known as Freiburg im Breisgau) or elsewhere as there is more than one. Which one do you mean? Rottenburg? or Rothenburg? You probably mean Rothenburg near Würzburg, known as Rothenburg ob der Tauber. You will need to ride at least some ICE trains to reach Freiburg im Breisgau and Rothenburg ob der Tauber.
3.) "If"? There are other interesting places, for sure. Cannot do that though. Only a few thousand characters are allowed in these posts. Check out some guidebooks to see what appeals to you, or rely on the pages Rick Steves has written on this website, which has a few of the many options.
https://www.ricksteves.com/europe/germany