I did that tour last Sept/Oct and it was wonderful! I also arrived from London the afternoon before the tour started.
May 2 is a Monday so there are lots of museums that are closed and in addition it is a 1st Monday of the month so the Musee Armee (Army Museum) is also closed then. I would go to the Cluny Museum which is open on Mondays and something else perhaps in the neighborhood of your hotel. Which hotel are you staying in for your tour?
On the back end, I would make sure you do the Marmottan Museum which is the museum with many Monets. You will have just been to Giverny and this collection will probably be interesting to you.
If you are interested in Asian art, the Guimet is also very good but without huge crowds.
Neither of these are off the beaten track altho they are smaller and don't draw the same kind of crowds as some of the other museums.
Somewhat off the beaten track is this walk in the 7th of Art Nouveau. This one is very convenient if your tour hotel is one of the ones Rick uses in the 7th.
http://www.parisperfect.com/blog/2011/03/art-nouveau-7th-arrondissement/
Or I also enjoyed walking thru a string of the covered passageways which are now filled with shops and restaurants. Very fun! I have one of the laminated Streetwise Maps of Paris and when I started looking for the addresses of them on there realized they were all marked in blue denoting a pedestrian walkway, so pretty easy to navigate. Here is a link to a few of them:
http://www.aviewoncities.com/paris/passages.htm
Have an excellent time! This is a fun tour with a variety of very interesting things to see. Do make sure you do Leonardo Da Vinci's home in Amboise on your free afternoon there.