Some of Lille is ok, some is a bit, well, hmmmm, nearly ok, IMHO.
If you go to the old town you can get some decent macarons and see some cool architecture, but a fair bit of the rest is not as old.
You will be near the birthplace of Paul, but unless you are already a convert to that particularly tasty but expensive French bakery, it won't mean much to you. London is saturated with Paul outlets so if it is new to you, try it in London and save some time. A nice Paul is next to St Pauls Cathedral in London (what a coincidence) and when the weather is decent at 9.30 am on a Sunday morning the outside tables make for a great perch for listening to the changes rung on St Pauls fabulous ring of bells.
But I digress. If you go to the old town of Lille, in fact much of the rest of Lille, be prepared for very narrow pavements (sidewalks) and almost none of the city is pedestrianised.
I like it well enough - I'll be there this week (but not for long) - but for a first timer I'd go for Paris. If you had one more day I'd suggest Brugge (Bruges) which isn't far from Brussels or Antwerpen.
Eurostar is easy, just get there a minimum of half an hour ahead and if you aren't checked in 30 before you won't go, I now always recommend an hour ahead.
Anyway - you will soon be hooked and it won't just be a day or two.