If you are interested in the bus from Aix to Toulon, you could pre-book on the "Zou région sud" website (not SNCF), but February is not peak season so I would not worry too much.
If you do not take the bus from Aix to Toulon, then the bus (or slower train) from Aix to Marseille & the train from Marseille to Hyères do not accept reservations (unless you take a TGV train but has it little added value, the regional trains are fine). You can still buy train tickets beforehand if that is easier for you.
For buses around Toulon & Hyères, the network is called Réseau Mistral. Those are city buses, no reservations possible.
If the bus timing does not work, you can find Uber at Hyères station, by the way. That would be a less-than-20€ ride to your destination.
As a recap, your options are:
- Bus (line 50) or train from Aix to Marseille, train from Marseille to Hyères (often direct), local bus or Uber/taxi to your accommodation
- Bus (ZOU line 59) from Aix to Toulon, then: A. taxi/Uber from Toulon, about 60€ (avoid at rush hour!!!) or B. train from Toulon to Hyères, then local bus or Uber/taxi as in option 1.
Personally, I would do 2A. or 2B.
2A. removes all the pain from the trip (outside of rush hour, traffic is abysmal in eastern Toulon), 2B. is the cheapest option of all and still faster or just as fast than going through Marseille.
From Hyères to St Raphael, you have to find your way back to Toulon station, and take a train there.