"There are four of us (teens and parents), so not sure how the carnet would work out."
Assuming you are all traveling together, one carnet would give you 2.5 trips, and two carnets would give you five trips. The carnet is just 10 single tickets bought together for a discount; each rider needs his/her own ticket. Two carnets would cost €27.40, and four Mobilis tickets would cost €28.
So, if you're definitely taking fewer than five trips, get carnets; if you're definitely taking 6 or more trips (3 round-trips), get the Mobilis; if you're taking 5 trips, it's a wash. Remember that the funicular up to Montmartre is a separate ticket, and if you take a Metro and then a bus, that's two of the individual tickets from the carnet; in these situations, the Mobilis starts to pay off fast. There's also the luxury of being able to take a short Metro ride without thinking about the cost; if you're just there one day, you're more likely to be zipping around in this way. I like to be able to hop on the Metro anytime, but others prefer walking more.
For getting in from the airport, since there are four of you, a taxi is probably best (not much more expensive than four RER tickets, and more comfortable as well). I have no personal experience, but others have posted that you can get Metro tickets at the airport information desk; just be sure you get the cheaper ones good for Paris only, not the more expensive ones good for more zones.