I'll try to help you onto the right track.
The RJ and S7 trains run every 30 minutes respectively from the airport to the city, i.e. there is a train departing every 15 minutes. Just board the next train, so you won't waste time waiting.
If it is an RJ train, go to Wien Hbf (main train station), take the U1 subway (red line) to Stephansplatz.
If it is an S7 train, go to Wien Mitte, take the U3 subway (orange line) to Stephansplatz.
I recommend buying all necessary tickets online in advance, obtain them as pdf files, print them and carry them with you. So you avoid any hassles with the ticket vending machines, saving valuable time.
For Vienna you correctly chose the one day ticket (€5.80 each), i.e. €11.60 in total.
https://shop.wienmobil.at/en/products/ONE_DAY
As a bearer of the one day ticket the ride to/from the airport is only €2, i.e. €8 in total.
https://shop.oebbtickets.at/en/ticket
Buying these tickets is a bit tricky. You must choose the approximate time slots, and when selecting "adult" the default will be "without discounts". You must click on "change", "add discount", expand the drop down menu, click on "Ticket Stadtverkehr Wien (Kernzone) ". (I guess that is deliberately so complicated just to make more profit.)
Therefore: Transportation €19.60 for 2 for the day.