There are several routes directly (ie not through Salzburg) to Zürich. The one through Lindau could be considered scenic, although I doubt that they are as much so as the route from Innsbruck through the Vorarlberg. That's also the fastest rail route and served by a direct EC.
Other routes between Munich go to Mannheim and up the Rhein to Basel. I've been on about all parts of that route at one time or another (although not the complete trip). I don't think it's particularly scenic.
Another route goes through the Schwäbisch Jura from Ulm to Schaffhausen. That's pretty, but not spectacular.
Lastly, there is one route that goes to Friedrichshafen and crosses Bodensee by ferry.
And, there is an IC Bus from the Bahn. It's the fastest connection, but they don't give route details.